🇵🇱 GŁÓWNY INSPEKTORAT OCHRONY ŚRODOWISKA PL

PCA AB 322 • Warszawa, Poland • 169 methods

Water & wastewaterEnvironmentMaterials & polymers

GŁÓWNY INSPEKTORAT OCHRONY ŚRODOWISKA is a laboratory accredited by PCA under number AB 322 (Warszawa, Poland). Its accreditation scope covers 169 test methods in the following areas: Water & wastewater, Environment, Materials & polymers. Test objects include: Water, Wastewater, Waste gases, Sewage sludge, Soil. Most frequently used techniques: Spectrophotometric method, Gravimetric method, Titrimetric method.

At a glance

  • Accreditation number: PCA AB 322
  • Methods in scope: 169
  • Types of test objects: 19
  • Techniques used: 33
  • City: Warszawa, Poland
Accreditation number
AB 322
Accreditation body
PCA
Address
ul. Chmielna 132/134, 00-805 Warszawa, CENTRALNE LABORATORIUM BADAWCZE, ODDZIAŁ W WARSZAWIE, ul. Bartycka 110 A
City
Warszawa, Poland

What this laboratory tests (19)

Analytical techniques used (33)

Laboratory locations

Certificate information

Issue date
17.11.2025
Issue no.
29

Accreditation scope — test methods (169)

No. Test object Methodology / Parameters Technique Reference document
Test methods
1 Wastewater Sampling for chemical, biological and physical testing Temperature of wastewater / of the sample taken
wastewater Range (1,0 – 50) oC
PN-ISO 5667-10:2021-11 | PN-77/C-04584
2 Groundwater Sampling for chemical and physical testing Temperature of water/of the water sample taken
Range (1,0 – 50) oC
PN-ISO 5667-11:2017-10 | PN-77/C-04584
3 Water Sampling for chemical and physical testing Temperature of water / of the water sample taken
Range (1,0 – 50) oC
PN-EN ISO 5667-6:2016-12 excluding cl. 7.5, 7.6 | PN-77/C-04584
4 Water Dissolved oxygen concentration
Range (0,5 – 15) mg/dm3
Electrochemical method PN-EN ISO 5814:2013
5 Water Electrical conductivity at 20 oC
Range (100 – 20000) μS/cm
Conductometric method PN-EN 27888:1999
6 Soil Sampling for chemical and physical testing PN-ISO 10381-4:2007 | PN-ISO 10381-5:2009
7 Water, Wastewater pH
Range 2,0 – 12,0
Potentiometric method PN-EN ISO 10523:2012
8 Waste Intervention testing (according to programme DAB-11) PB-11/CLB issue 1 of 25.09.2023
9 Sewage sludge Sampling for chemical, physical and biological testing PN-EN ISO 5667-13:2011
10 Waste gases Sampling for determination of the dust fraction PN-Z-04030-7:1994 | PN-EN 13284-1:2018-02
11 Waste gases Emission of dust fractions ( calculated) PN-Z-04030-7:1994 | PN-EN 13284-1:2018-02
12 Waste gases Dust sampling for determination of heavy metals in dust PN-Z-04030-7:1994
13 Waste gases Emission of heavy metals in dust (calculated) PN-Z-04030-7:1994
14 Dust samples Share of dust fractions (particle size distribution) including PM2,5 and PM10
Range (0,1 – 100) μm Range (0 – 100) %
Laser diffraction method with liquid dispersion ISO 13320:2020
15 General environment – noise from installations, equipment and industrial plants A-weighted equivalent sound pressure level
Range (24 – 135) dB
Direct measurement method Annex 7 to the Regulation of the Minister of Climate and Environment of 07.09.2021 (consolidated text Journal of Laws of 2023, item 1706) excluding cl. F
16 General environment – noise from installations, equipment and industrial plants A-weighted equivalent sound pressure level for the reference time T expressed by the indicators LAeqD and LAeqN (calculated) Annex 7 to the Regulation of the Minister of Climate and Environment of 07.09.2021 (consolidated text Journal of Laws of 2023, item 1706) excluding cl. F
17 General environment – impulse noise from installations, equipment and industrial plants A-weighted equivalent sound pressure level
Range (24 – 135) dB
Direct measurement method Annex 8 to the Regulation of the Minister of Climate and Environment of 07.09.2021 (consolidated text Journal of Laws of 2023, item 1706)
18 General environment – impulse noise from installations, equipment and industrial plants A-weighted equivalent sound pressure level for the reference time T expressed by the indicators LAeqD and LAeqN (calculated) Annex 8 to the Regulation of the Minister of Climate and Environment of 07.09.2021 (consolidated text Journal of Laws of 2023, item 1706)
19 General environment – noise from roads, railway lines, tram lines A-weighted equivalent sound level A-weighted sound exposure level
Range (24 – 135) dB
Direct measurement method Annex 3 to the Regulation of the Minister of the Environment of 16.06.2011 (Journal of Laws 2011 No. 140 item 824 and No. 288, item 1697) excluding cl. H
20 General environment – noise from roads, railway lines, tram lines A-weighted equivalent sound pressure level for the reference time T expressed by the indicators LAeqD and LAeqN (calculated) Annex 3 to the Regulation of the Minister of the Environment of 16.06.2011 (Journal of Laws 2011 No. 140 item 824 and No. 288, item 1697) excluding cl. H
21 General environment – noise from airports A-weighted sound exposure level A-weighted equivalent sound level
Range (24 – 130) dB
Direct measurement method Annex 2 to the Regulation of the Minister of the Environment of 16.06.2011 (Journal of Laws 2011 No. 140, item 824) excluding cl. H
22 General environment – noise from airports A-weighted equivalent sound pressure level for the reference time T expressed by the indicators LAeqD and LAeqN (calculated) Annex 2 to the Regulation of the Minister of the Environment of 16.06.2011 (Journal of Laws 2011 No. 140, item 824) excluding cl. H
23 Environment – electromagnetic field in the vicinity of electric power substations and power lines Electric field strength:
in the frequency range 50 Hz Range (1,0 – 20000) V/m
Direct measurement method Annex to the Regulation of the Minister of Climate of 17.02.2020 (Journal of Laws 2022 item 2630)
24 Environment – electromagnetic field in the vicinity of electric power substations and power lines Magnetic flux density:
in the frequency range 50 Hz Range 1μT – 10 mT
Direct measurement method Annex to the Regulation of the Minister of Climate of 17.02.2020 (Journal of Laws 2022 item 2630)
25 Environment – electromagnetic field in the vicinity of electric power substations and power lines Magnetic field strength:
in the frequency range 50 Hz (calculated)
Annex to the Regulation of the Minister of Climate of 17.02.2020 (Journal of Laws 2022 item 2630)
26 Environment – electromagnetic field in the vicinity of radiocommunication installations (broadband measurements) Electric field strength:
in the frequency range: from 10 MHz up to 40 GHz Range (0,8 – 300) V/m
Direct measurement method Annex to the Regulation of the Minister of Climate of 17.02.2020 (Journal of Laws 2022 item 2630)
27 Environment – electromagnetic field in the vicinity of radiocommunication installations (broadband measurements) Magnetic field strength:
in the frequency range from 10 MHz up to 40 GHz (calculated)
Clause 3 of the Annex to the Regulation of the Minister of Climate of 17.02.2020 (Journal of Laws 2022 item 2630)
28 Waste gases Gas volume flow rate for dynamic pressures >10Pa
Gas velocity Range (1,0 – 6) m/s
Stagnation pressure method; Anemometric method PN-Z-04030-7:1994
29 Waste gases Sampling for determination of dust concentration PN-Z-04030-7:1994
30 Waste gases Dust concentration
Range (0,001 – 100) g/m3
Gravimetric method PN-Z-04030-7:1994
31 Waste gases Dust emission (calculated) PN-Z-04030-7:1994
32 Waste gases Gas velocity and volume flow for differential pressures >5 Pa Differential pressure measurement method PN-EN ISO 16911-1:2013-07 CEN/TR 17078:2017-03
33 Waste gases Gas velocity
Range (1,0 – 6) m/s
Anemometric method PN-EN ISO 16911-1:2013-07 CEN/TR 17078:2017-03
34 Waste gases Sampling for determination of dust concentration PN-EN 13284-1:2018-02
35 Waste gases Dust concentration
Range (1,0 – 50) mg/m3
Gravimetric method PN-EN 13284-1:2018-02
36 Waste gases Dust emission (calculated) PN-EN 13284-1:2018-02
37 Waste gases Carbon monoxide concentration
CO (5 – 2900) mg/m3
Non-dispersive infrared spectrometry (NDIR) PN-ISO 10396:2001 | PN-EN 15058:2017-04
38 Waste gases Carbon monoxide emission (calculated) PN-ISO 10396:2001 | PN-EN 15058:2017-04
39 Waste gases Water vapour concentration (H2O)
Range (4,0 - 40,0) % Water vapour content Range (29 -250 ) g/m3
Condensation-adsorption method PN-EN 14790:2017-04
40 Waste gases Concentration of: sulphur dioxide, carbon dioxide
SO2 (9 – 3000) mg/m3 CO2 (0,1 – 21) %
Non-dispersive infrared spectrometry (NDIR) PN-ISO 10396:2001
41 Waste gases Emission: SO2, CO2 (calculated) PN-ISO 10396:2001
42 Waste gases Mass concentration of total organic carbon (TVOC)
Range (2 – 500) mg/m3
Continuous measurement method with flame ionization detection FID PN-EN 12619:2013
43 Waste gases Emission of total organic carbon (TVOC) (calculated) PN-EN 12619:2013
44 Waste gases Oxygen concentration
Range (0,1 – 21,0) %
Paramagnetic method PN-ISO 10396:2001 | PN-EN 14789:2017-04
45 Waste gases Concentration of nitrogen monoxide, nitrogen oxides
NO (2,0 – 1500) mg/m3 NOx (3,0 – 2100) mg/m3
Chemiluminescence method PN-ISO 10396:2001 | PN-EN 14792:2017-04
46 Waste gases Emission: NO, NOx (NO and NO2 calculated as NO2) (calculated) PN-ISO 10396:2001 | PN-EN 14792:2017-04
47 Waste gases Sampling for the determination of concentrations of individual gaseous organic compounds Aspiration method using activated carbon PN-EN 13649:2005
48 Waste gases Emission of individual gaseous organic compounds (calculated) PN-EN 13649:2005
49 Waste gases Sampling for determination of concentrations of organic compounds Aspiration method using activated carbon and silica gel PN-Z-04008-4:1999
50 Waste gases Emission of organic compounds (calculated) PN-Z-04008-4:1999
51 Water, Wastewater Permanganate index
Range (0,5 – 50) mg/dm3 O2
Titrimetric method PN-EN ISO 8467:2001
52 Water, Wastewater Chemical oxygen demand
COD-Cr Range (10,0 – 4000) mg/dm3 O2
Spectrophotometric method PN-ISO 15705:2005
53 Water, Wastewater Biochemical oxygen demand
BOD5 Range (0,5 – 6,0) mg/dm3 O2
Electrochemical method PN-EN 1899-2:2002
54 Water, Wastewater Biochemical oxygen demand
BOD5 Range (1,0 – 6000) mg/dm3 O2
Electrochemical method PN-EN ISO 5815-1:2019-12
55 Water, Wastewater Ammonium nitrogen concentration
Range (1,00 – 100) mg/dm3
Titrimetric method PN-ISO 5664:2002
56 Water, Wastewater Nitrite nitrogen concentration
Range (0,010 – 10) mg/dm3
Spectrophotometric method PN-EN 26777:1999
57 Water, Wastewater Kjeldahl nitrogen concentration
Range (0,50 – 500) mg/dm3
Titrimetric method PN-EN 25663:2001
58 Water, Wastewater Total nitrogen concentration (calculated) PB-049/WA issue 3 of 15.07.2019
59 Water, Wastewater Total dissolved solids (TDS)
Range (50,0 – 2000) mg/dm3
Gravimetric method PN-EN 15216:2022-03
60 Water, Wastewater Total suspended solids (TSS)
Range (2,0 – 2000) mg/dm3
Gravimetric method PN-EN 872:2007+Ap1:2007
61 Water, Wastewater Total hardness (calculated) PB-060/WA issue 2 of 15.07.2019
62 Water, Wastewater Total phosphorus concentration
Range (0,040 – 56,0) mg/dm3
Spectrophotometric method PN-EN ISO 6878:2006 +Ap1:2010+Ap2:2010
63 Water, Wastewater Concentration of substances extractable with petroleum ether
Range (0,5 – 2000) mg/dm3
Gravimetric method PN-86/C-04573.01
64 Water, Wastewater Total organic carbon concentration
Range (2,00 – 500) mg/dm3
Spectrometry method in the infrared range (IR) PN-EN 1484:1999
65 Water, Wastewater Mineral oil index
Range (0,1 – 50) mg/dm3
Gas chromatography with flame ionization detection (GC-FID) PN-EN ISO 9377-2:2003
66 Water, Wastewater Ammonium nitrogen concentration
Range (0,05 – 5,0) mg/dm3
Continuous flow analysis (CFA) with spectrophotometric detection PN-EN ISO 11732:2007 excluding cl. 3
67 Water, Wastewater Nitrate nitrogen concentration
Range (0,10 – 50) mg/dm3
Continuous flow analysis (CFA) with spectrophotometric detection PN-EN ISO 13395:2001
68 Water, Wastewater Nitrite nitrogen concentration
Range (0,003 – 1,0) mg/dm3
Continuous flow analysis (CFA) with spectrophotometric detection PN-EN ISO 13395:2001
69 Water, Wastewater Total phosphorus concentration
Range (0,050 – 50,0) mg/dm3
Inductively coupled plasma optical emission spectrometry (ICP-OES) PN-EN ISO 11885:2009
70 Water, Wastewater Phenol index / volatile phenols concentration
Range (0,003 – 0,50) mg/dm3
Continuous flow analysis (CFA) with spectrophotometric detection PN-EN ISO 14402:2004 excluding cl. 3
71 Water, Wastewater Total and free cyanide concentration
Range (0,005 – 5,0) mg/dm3
Flow injection analysis (FIA) with spectrophotometric detection PN-EN ISO 14403-1:2012
72 Water, Wastewater Combined cyanide concentration (calculated) PB-075/WA issue 1 of 01.06.2022
73 Water, Wastewater Metal concentrations
chromium (0,0010 – 1,00) mg/dm3 lead (0,0010 – 1,00) mg/dm3 copper (0,0010 – 1,00) mg/dm3 cadmium (0,00010 – 1,00) mg/dm3 nickel (0,0010 – 1,00) mg/dm3 boron (0,011 – 10,0) mg/dm3 barium (0,0030 – 1,00) mg/dm3 selenium (0,0010 – 10,0) mg/dm3 sodium (0,050 – 900,0) mg/dm3 molybdenum (0,0010 – 1,00) mg/dm3 calcium (0,10 – 450,0) mg/dm3 zinc (0,0020 – 10,0) mg/dm3 manganese (0,0030 – 1,00) mg/dm3 arsenic (0,0010 – 10,0) mg/dm3 iron (0,020 – 10,0) mg/dm3 aluminium (0,0050 – 1,00) mg/dm3 magnesium (0,10 – 90,0) mg/dm3 potassium (0,20 – 90,0) mg/dm3
Inductively coupled plasma mass spectrometry (ICP-MS) PN-EN ISO 17294-2:2024-04
74 Water, Wastewater Anion concentrations
fluorides (0,10 – 14) mg/dm3 chlorides (0,50 – 400) mg/dm3 nitrites (0,50 – 12) mg/dm3 nitrates (0,50 – 200) mg/dm3 sulfates (0,50 – 600) mg/dm3
Ion chromatography with conductometric detection (IC-CD) PN-EN ISO 10304-1:2009+AC:2012
75 Water, Wastewater Non-ionic surfactant concentration (non-ionic surface active agents)
Range (0,200 – 12,0) mg/dm3
Spectrophotometric method PB-058/WA issue 4 of 15.07.2019
76 Water, Wastewater Concentration of volatile organic compounds
dichloromethane (0,50 – 100) μg/dm3 trichloromethane (0,50 – 100) μg/dm3 tetrachloromethane (0,50 – 100) μg/dm3 Range 1,2-dichloroethane (0,50 – 100) μg/dm3 trichloroethylene (0,50 – 100) μg/dm3 tetrachloroethylene (0,50 – 100) μg/dm3 hexachlorobutadiene (0,010 – 100) μg/dm3 benzene (0,50 – 100) μg/dm3 toluene (0,50 – 100) μg/dm3 ethylbenzene (0,50 – 100) μg/dm3 xylene (sum of isomers) (1,0 – 100) μg/dm3 1,2,3-trichlorobenzene (0,010 – 100) μg/dm3 1,2,4-trichlorobenzene (0,010 – 100) μg/dm3 1,3,5-trichlorobenzene (0,010 – 100) μg/dm3 naphthalene (0,10 – 100) μg/dm3
Gas chromatography with purge and trap technique (Purge&Trap) and mass spectrometry detection (P&T GC-MS) PN-EN ISO 15680:2008
77 Water, Wastewater Polychlorinated biphenyls (PCB) concentration
PCB 28 (0,010 – 0,050) μg/dm3 PCB 52 (0,010 – 0,050) μg/dm3 PCB 101 (0,010 – 0,050) μg/dm3 PCB 118 (0,010 – 0,050) μg/dm3 PCB 138 (0,010 – 0,050) μg/dm3 PCB 153 (0,010 – 0,050) μg/dm3 PCB 180 (0,010 – 0,050) μg/dm3 PCB 194 (0,010 – 0,050) μg/dm3
Gas chromatography with electron capture detection (GC-ECD) PN-EN ISO 6468:2002
78 Water, Wastewater Chlorobenzene concentration
Range 1,2,3-trichlorobenzene Range (0,002 – 0,100) μg/dm3 1,2,4-trichlorobenzene (0,002 – 0,100) μg/dm3 1,3,5-trichlorobenzene (0,002 – 0,100) μg/dm3 pentachlorobenzene (0,002 – 0,050) μg/dm3 hexachlorobenzene (0,002 – 0,050) μg/dm3
Gas chromatography with electron capture detection (GC-ECD) PN-EN ISO 6468:2002
79 Water, Wastewater Pesticide concentration
hexachlorocyclohexane (sum of α,β,γ,δ isomers) Range (0,002 – 0,050) μg/dm3 aldrin (0,002 – 0,050) μg/dm3 dieldrin (0,002 – 0,050) μg/dm3 endrin (0,002 – 0,050) μg/dm3 isodrin (0,002 – 0,050) μg/dm3 α-endosulfan (0,002 – 0,050) μg/dm3 β-endosulfan (0,002 – 0,050) μg/dm3 p,p-DDE (0,002 – 0,050) μg/dm3 p,p-DDD (0,002 – 0,050) μg/dm3 p,p-DDT (0,002 – 0,050) μg/dm3 o,p-DDT (0,002 – 0,050) μg/dm3 alachlor (0,005 – 0,050) μg/dm3 trifluralin (0,002 – 0,050) μg/dm3 chlorfenvinphos (0,005 – 0,050) μg/dm3 chlorpyrifos-ethyl (0,002 – 0,050) μg/dm3
Gas chromatography with electron capture detection (GC-ECD) PN-EN ISO 6468:2002
80 Water, Wastewater Chloride concentration
Range (5,00 – 1000) mg/dm3
Titrimetric method PN-ISO 9297:1994
81 Water Mercury concentration
Range (15,0 – 500) ng/dm3
Atomic fluorescence spectrometry (AFS) PN-EN ISO 17852:2009
82 Water Hexavalent chromium concentration
Range (0,0050 – 1,00) mg/dm3
Inductively coupled plasma mass spectrometry (ICP-MS) PB-062/WA issue 2 of 15.07.2019
83 Water Phosphate concentration
Range (0,06 – 14,0) mg/dm3
Spectrophotometric method PN-EN ISO 6878:2006+Ap1:2010+Ap2:2010
84 Water Orthophosphate concentration
Range (0,10 – 14) mg/dm3
Ion chromatography with conductometric detection (IC-CD) PN-EN ISO 10304-1:2009+AC:2012
85 Wastewater Mercury concentration
Range (15,0 – 1000) ng/dm3
Atomic fluorescence spectrometry (AFS) PN-EN ISO 17852:2009
86 Sewage sludge Presence and count of viable eggs of intestinal parasites Ascaris sp.,Toxocara sp., Trichuris sp.,
Range from 20 eggs/kg
Flotation method, microscopic PB-09/CLB issue 1 of 30.05.2022
87 Sewage sludge Metal content
chromium (1,5 – 600) mg/kg lead (0,90 – 1200) mg/kg copper (1,2 – 800) mg/kg cadmium (0,25 – 1000) mg/kg nickel (0,90 – 600) mg/kg zinc (9,0 – 2200) mg/kg magnesium (20,0 – 23 000) mg/kg calcium (150 – 110 000) mg/kg
Inductively coupled plasma mass spectrometry (ICP-MS) PN-EN 13346:2002
88 Sewage sludge Kjeldahl nitrogen content
Range (0,10 – 10,0) % Range (1,0 – 100) g/kg
Titrimetric method PN-EN 13342:2002
89 Sewage sludge Ammonium nitrogen content
Range (0,10 – 5,00) % Range (1,00 – 50,0) g/kg
Titrimetric method PB-068/WA issue 2 of 15.07.2019
90 Sewage sludge Dry residue / water content
Range (0,1 – 99,9) %
Gravimetric method PN-EN 12880:2004
91 Sewage sludge Total phosphorus content
Range (0,3 – 6,0) % Range (3,0 – 60) g/kg
Spectrophotometric method PN-EN 16174:2012 | PN-EN ISO 6878:2006 +Ap1:2010+Ap2:2010 cl. 7
92 Sewage sludge Total phosphorus content
Range (0,3 – 8,0) % Range (3,0 – 80) g/kg
Inductively coupled plasma mass spectrometry (ICP-MS) PN-EN 16171:2017-02
93 Soil Metal content
arsenic (2 – 4000) mg/kg barium (3,0 – 400) mg/kg chromium (1,5 – 400) mg/kg zinc (9,0 – 4000) mg/kg cadmium (0,10 – 400) mg/kg copper (0,90 – 400) mg/kg molybdenum (0,50 – 400) mg/kg lead (0,90 – 400) mg/kg nickel (0,90 – 400) mg/kg cobalt (0,2 – 500 ) mg/kg tin (1,5 – 500 ) mg/kg
Inductively coupled plasma mass spectrometry (ICP-MS) PB-059/WA issue 4 of 15.07.2019
94 Soil Total organic carbon (TOC) content
Range (4 000 – 400 000) mg/kg Range (0,400 – 40,0) %
Infrared spectrometry method (IR) PN-EN 10694:2002 excluding cl. 8.2.1
95 Soil Petrol content (C6-C12 hydrocarbons) / sum of C6-C12 hydrocarbons, components of the petrol fraction
Range (1,0 – 500) mg/kg
Gas chromatography with purge and trap technique (Purge&Trap) and mass spectrometry detection (P&T GC-MS) PB-067/WA issue 3 of 01.07.2023
96 Soil Dry matter content / water content
Range (0,1 – 99,9) %
Gravimetric method PN-ISO 11465:1999
97 Soil pH - in H2O
Range 3,0 – 10,0 Range 3,0 – 10,0
Potentiometric method pH - in KCl; Potentiometric method PN-EN ISO 10390:2022-09
98 Soil, Sewage sludge Mercury content
Range (0,040 – 6,00) mg/kg
Atomic absorption spectrometry with amalgamation technique PB-026/WA issue 7 of 15.07.2019
99 General environment: - waste gas samples Metal content in dust
arsenic (0,10 – 140) μg/sample cadmium (0,10 – 130) μg/sample chromium (0,60 – 250) μg/sample cobalt (0,20 – 25) μg/sample copper (4,0 – 500) μg/sample manganese (0,70 – 300) μg/sample nickel (1,2 – 70) μg/sample lead (0,15 – 2300) μg/sample thallium (0,10 – 14) μg/sample vanadium (0,10 – 25) μg/sample iron (40 – 6000) μg/sample zinc (17 – 8000) μg/sample
Inductively coupled plasma mass spectrometry (ICP-MS) PN-EN 14385:2005
100 Surface water Chlorophyll a concentration
Range (1,1 – 300) μg/dm3
Spectrophotometric method PN-ISO 10260:2002
101 Water, Wastewater Permanganate index
Range (1,3 – 200) mg/dm3 O2
Titrimetric method PN-EN ISO 8467:2001
102 Water, Wastewater Chloride concentration
Range (5,00 – 2000) mg/dm3
Titrimetric method PN-ISO 9297:1994
103 Water, Wastewater Sulfate concentration
Range (10,0 – 5000) mg/dm3
Gravimetric method PN-ISO 9280:2002
104 Water, Wastewater Ammonium nitrogen concentration
Range (0,05 – 100) mg/dm3
Spectrophotometric method PN-ISO 7150-1:2002
105 Water, Wastewater Nitrate nitrogen concentration
Range (0,04 – 100) mg/dm3
Spectrophotometric method PN-82/C-04576/08
106 Water, Wastewater Kjeldahl nitrogen concentration
Range (0,50 – 300) mg/dm3
Titrimetric method PN-EN 25663:2001
107 Water, Wastewater Total nitrogen concentration (calculated) PB-049/WA issue 3 of 15.07.2019
108 Water, Wastewater Total dissolved solids (TDS)
Range (20,0 – 2000) mg/dm3
Gravimetric method PN-EN 15216:2022-03
109 Water, Wastewater Total hardness (calculated) PB-060/WA issue 2 of 15.07.2019
110 Water, Wastewater Biochemical oxygen demand
BOD5 Range (1,0 – 6000) mg/dm3 O2
Electrochemical method PN-EN ISO 5815-1:2019-12
111 Water, Wastewater Biochemical oxygen demand
BOD5 Range (0,8 – 6,0) mg/dm3 O2
Electrochemical method PN-EN 1899-2:2002
112 Water, Wastewater Total suspended solids (TSS)
Range (5,0 – 5000) mg/dm3
Gravimetric method PN-EN 872:2007+Ap1:2007
113 Water, Wastewater Nitrite nitrogen concentration
Range (0,005 – 100) mg/dm3
Spectrophotometric method PN-EN 26777:1999
114 Water, Wastewater Orthophosphate concentration
Range (0,050 – 100) mg/dm3 P
Spectrophotometric method PN-EN ISO 6878:2006+Ap1:2010+Ap2:2010 cl. 4
115 Water, Wastewater Total phosphorus concentration
Range (0,050 – 100) mg/dm3
Spectrophotometric method PN-EN ISO 6878:2006 +Ap1:2010+Ap2:2010 cl. 7
116 Water, Wastewater Total organic carbon concentration
Range (1,0 – 1000) mg/dm3
Spectrometry method in the infrared range (IR) PN-EN 1484:1999
117 Water, Wastewater Chemical oxygen demand
COD-Cr Range (10,0 – 1000) mg/dm3 O2
Spectrophotometric method PN-ISO 15705:2005
118 Water, Wastewater Pesticide concentration
aldrin (0,003 – 0,03) μg/dm3 dieldrin (0,003 – 0,03) μg/dm3 endrin (0,003 – 0,03) μg/dm3 isodrin (0,003 – 0,03) μg/dm3 p,p’-DDE (0,003 – 0,03) μg/dm3 p,p’-DDD (0,003 – 0,03) μg/dm3 p,p’-DDT (0,003 – 0,03) μg/dm3 o,p’-DDT (0,003 – 0,03) μg/dm3 DDT - total Range (0,003 – 0,03) μg/dm3 1,2,3-trichlorobenzene (0,004 – 0,04) μg/dm3 1,2,4-trichlorobenzene (0,004 – 0,04) μg/dm3 1,3,5-trichlorobenzene (0,004 – 0,04) μg/dm3 TCB - sum (0,004 – 0,04) μg/dm3 pentachlorobenzene (0,002 – 0,02) μg/dm3 hexachlorobenzene (0,002 – 0,02) μg/dm3 α-HCH (0,003 – 0,03) μg/dm3 β-HCH (0,003 – 0,03) μg/dm3 γ-HCH (0,003 – 0,03) μg/dm3 δ-HCH (0,003 – 0,03) μg/dm3 HCH - sum (0,003 – 0,03) μg/dm3 α – endosulfan (0,0015 – 0,015) μg/dm3 β – endosulfan (0,0015 – 0,015) μg/dm3 endosulfan – sum (0,0015 – 0,015) μg/dm3 pesticides - total (total DDT and γ-HCH) (0,003 – 0,03) μg/dm3
Gas chromatography with electron capture detection (GC-ECD) PN-EN ISO 6468:2002
119 Water, Wastewater Anion concentrations
chlorides (0,10 – 200) mg/dm3 nitrites (0,010 – 16 ) mg/dm3 nitrates (0,10 – 86) mg/dm3 orthophosphates (0,061 – 5,0) mg/dm3 sulfates (0,10 – 200) mg/dm3 fluorides (0,010 – 0,50) mg/dm3
Ion chromatography with conductometric detection (IC-CD) PN-EN ISO 10304-1:2009+AC:2012
120 Water, Wastewater Concentration of substances extractable with petroleum ether
Range (1,0 – 50) mg/dm3
Gravimetric method PN-86/C-04573/01
121 Water, Wastewater Cation concentrations:
ammonium nitrogen (0,050 – 3,0) mg/dm3 calcium (0,50 – 80) mg/dm3 magnesium (0,50 – 40) mg/dm3
Ion chromatography with conductometric detection (IC-CD) PN-EN ISO 14911:2002
122 Water, Wastewater Mineral oil index
Range (0,06 – 600) mg/dm3
Gas chromatography with flame ionization detection (GC-FID) PN-EN ISO 9377-2:2003
123 Sewage sludge Presence and count of viable eggs of intestinal parasites Ascaris sp.,Toxocara sp., Trichuris sp.,
Range from 20 eggs/kg
Flotation method, microscopic PB-09/CLB issue 1 of 30.05.2022
124 Sewage sludge Dry residue / water content
Range (0,1 – 99,9) %
Gravimetric method PN-EN 12880:2004
125 Sewage sludge Loss on ignition / organic matter content
Range (0,1 – 80,0) %
Gravimetric method PN-EN 15935:2022-01
126 Sewage sludge pH - in H2O
Range 2,0 – 12,0
Potentiometric method PN-EN ISO 10390:2022-09
127 Waste code: 20 03 03 19 13 03 17 05 03 Mineral oil content (C10-C40 hydrocarbons)
Range (50 – 10 000) mg/kg
Gas chromatography with flame ionization detection (GC-FID) PN-EN 14039:2008
128 Soil Mineral oil content (C12-C35 hydrocarbons) / sum of C12 – C35 hydrocarbons, components of the oil fraction
Range (50 – 10 000) mg/kg
Gas chromatography with flame ionization detection (GC-FID) PN-EN ISO 16703:2011
129 Soil Dry matter content / water content
Range (0,1 – 99,9)%
Gravimetric method PN-ISO 11465:1999
130 Soil Pesticides content aldrin (0,2 – 120) μg/kg dieldrin (0,2 – 400) μg/kg endrin (0,2 – 400) μg/kg p,p’-DDE (0,2 – 120) μg/kg p,p’-DDD (0,2 – 120) μg/kg p,p’-DDT (0,2 – 250) μg/kg o,p’-DDT (0,2 – 250) μg/kg, total DDT (0,2 – 250) μg/kg α-HCH (0,2 – 400) μg/kg β-HCH (0,2 – 300) μg/kg γ-HCH (0,2 – 300) μg/kg Gas chromatography with electron capture detection (GC-ECD) PN-ISO 10382:2007
131 Soil pH
Range 2,0 – 12,0
Potentiometric method PN-EN ISO 10390:2022-09
132 Water Total calcium and magnesium content ( total hardness)
Range (5,0 – 1000) mg/dm3 CaCO3
Titrimetric method PN-ISO 6059:1999
133 Water Total organic carbon concentration
Range (0,50 – 1000) mg/dm3
Spectrometry method in the infrared range (IR) PN-EN 1484:1999
134 Water Chlorophyll a concentration
Range (1,1 – 350) μg/dm3
Spectrophotometric method PN-ISO 10260:2002
135 Water, Wastewater Ammonium nitrogen concentration
Range (0,05 – 200) mg/dm3
Spectrophotometric method PN-ISO 7150-1:2002
136 Water, Wastewater Nitrate nitrogen concentration
Range (0,10 – 200) mg/dm3 Nitrate concentration (0,44 – 886) mg/dm3
Spectrophotometric method PN-82/C-04576/08
137 Water, Wastewater Nitrite nitrogen concentration
Range (0,0024 – 10) mg/dm3 Nitrite concentration (0,060 – 250) mg/dm3
Spectrophotometric method PN-EN 26777:1999
138 Water, Wastewater Kjeldahl nitrogen concentration
Range (0,20 – 1000) mg/dm3
Spectrophotometric method PN-EN 25663:2001
139 Water, Wastewater Total nitrogen concentration (calculated) PB-049/WA issue 3 of 15.07.2019
140 Water, Wastewater Chloride concentration
Range (5,0 – 2000) mg/dm3
Titrimetric method PN-ISO 9297:1994
141 Water, Wastewater Permanganate index
Range (0,85 – 200) mg/dm3 O2
Titrimetric method PN-EN ISO 8467:2001
142 Water, Wastewater Dissolved phosphate concentration
Range (0,025 – 240) mg/dm3
Spectrophotometric method PN-EN ISO 6878:2006+Ap1:2010+ Ap2:2010 cl. 4
143 Water, Wastewater Total phosphorus concentration
Range (0,010 – 80) mg/dm3
Spectrophotometric method PN-EN ISO 6878:2006+Ap1:2010+ Ap2:2010 cl. 4, cl. 7, cl. 8
144 Water, Wastewater Total dissolved solids (TDS)
Range (50,0 – 10000) mg/dm3
Gravimetric method PN-EN 15216:2022-03
145 Water, Wastewater Total suspended solids (TSS)
Range (5,0 – 1000) mg/dm3
Gravimetric method PN-EN 872:2007+Ap1:2007
146 Water, Wastewater Sulfate concentration
Range (5,0 – 2000) mg/dm3
Gravimetric method PN-ISO 9280:2002
147 Water, Wastewater Hexavalent chromium concentration
Range (0,0080 – 100) mg/dm3
Spectrophotometric method PN-77/C-04604.08
148 Water, Wastewater Biochemical oxygen demand
BOD5 Range (1,0 – 6,0) mg/dm3 O2
Electrochemical method PN-EN 1899-2:2002
149 Water, Wastewater Biochemical oxygen demand
BOD5 Range (1,0 – 6000) mg/dm3 O2
Electrochemical method PN-EN ISO 5815-1:2019-12
150 Water, Wastewater Anionic surfactant concentration
Range (0,10 – 50) mg/dm3
Spectrophotometric method PN-EN 903:2002
151 Water, Wastewater Concentration of substances extractable with petroleum ether
Range (1,0 – 200) mg/dm3
Gravimetric method PN-86/C-04573.01
152 Water, Wastewater Anion concentrations:
chlorides (0,50 – 70,0) mg/dm3 nitrites (0,50 – 50,0) mg/dm3 nitrates (0,50 – 70,0) mg/dm3 orthophosphates (0,50 – 70,0) mg/dm3 sulfates (0,50 – 70,0) mg/dm3 fluorides (0,10 – 14) mg/dm3
Ion chromatography with conductometric detection (IC-CD) PN-EN ISO 10304-1:2009+AC:2012
153 Water, Wastewater Ammonium nitrogen concentration
Range (0,080 – 4,0) mg/dm3
Ion chromatography with conductometric detection (IC-CD) PN-EN ISO 14911:2002
154 Water, Wastewater Chemical oxygen demand
COD-Cr Range (10,0 – 5000) mg/dm3 O2
Spectrophotometric method PN-ISO 15705:2005
155 Water, Wastewater Concentration of polycyclic aromatic hydrocarbons
naphthalene (0,0020 – 100) μg/dm3 anthracene (0,0010 – 100) μg/dm3 fluoranthene (0,0020 – 100) μg/dm3 benzo(b)fluoranthene Range (0,0010 – 100) μg/dm3 benzo(k)fluoranthene (0,0005 – 50) μg/dm3 benzo(a)pyrene (0,0010 – 100) μg/dm3 dibenzo(ah)anthracene (0,001 – 100) μg/dm3 benzo(ghi)perylene (0,0014 – 100) μg/dm3 indeno (1,2,3-cd)pyrene (0,001 – 100) μg/dm3
High-performance liquid chromatography with fluorescence detection (HPLC-FLD) PB-072/WA issue 1 of 28.09.2020
156 Water, Wastewater Aromatic hydrocarbons (BTEX) concentration
benzene (1,5 – 10 000) μg/dm3 toluene (1,5 – 10 000) μg/dm3 ethylbenzene (1,5 – 10 000) μg/dm3 mp-xylene (1,5 – 10 000) μg/dm3 o-xylene (1,5 – 10 000) μg/dm3 styrene (1,5 – 10 000) μg/dm3
Headspace gas chromatography with flame ionization detection (HS-GC-FID) PN-ISO 11423-1:2002
157 Water, Wastewater Sum of BTEX (calculated) PN-ISO 11423-1:2002
158 Soil Aromatic hydrocarbons (BTEX) concentration
benzene (0,075 – 200) mg/kg toluene (0,075 – 200) mg/kg ethylbenzene (0,075 – 200) mg/kg mp-xylene (0,075 – 200) mg/kg o-xylene (0,075 – 200) mg/kg styrene (0,075 – 200) mg/kg
Headspace gas chromatography with flame ionization detection (HS-GC-FID) PN-EN ISO 22155:2016-07
159 Soil Sum of BTEX (calculated) PN-EN ISO 22155:2016-07
160 Soil Dry matter content / water content
Range (0,1 – 99,9) %
Gravimetric method PN-ISO 11465:1999
161 Soil pH
Range 3,0 – 11,0
Potentiometric method PN-EN ISO 10390:2022-09
162 Soil Concentration of polycyclic aromatic hydrocarbons
naphthalene (0,0010 – 100) mg/kg phenanthrene (0,0010 – 100) mg/kg anthracene (0,0010 – 100) mg/kg fluoranthene (0,0010 – 100) mg/kg benzo(a)anthracene Range (0,0010 – 100) mg/kg chrysene (0,0010 – 100) mg/kg benzo(a)fluoranthene (0,0010 – 100) mg/kg benzo(a)pyrene (0,0010 – 100) mg/kg benzo(ghi)perylene (0,0010 – 100) mg/kg benzo(b)fluoranthene (0,0010 – 25) mg/kg benzo(k)fluoranthene (0,00050 – 25) mg/kg dibenzo(ah)anthracene (0,0010 – 25) mg/kg indeno (1,2,3-cd)pyrene (0,0010 – 25) mg/kg
High-performance liquid chromatography with fluorescence detection (HPLC-FLD) PB-072/WA issue 1 of 28.09.2020
163 Wastewater Presence and count of viable eggs of intestinal parasites Ascaris sp.,Toxocara sp., Trichuris sp.,
Range from 1 egg/ dm3
Flotation method, microscopic PB-073/WA issue 2 of 30.05.2022
164 Sewage sludge Presence and count of viable eggs of intestinal parasites Ascaris sp.,Toxocara sp., Trichuris sp.,
Range from 20 eggs/ kg
Flotation method, microscopic PB-09/CLB issue 1 of 30.05.2022
165 Sewage sludge Dry residue / water content/dry matter
Range (0,1 – 99,9) %
Gravimetric method PN-EN 12880:2004
166 Sewage sludge pH
Range 3,0 – 11,0
Potentiometric method PN-EN ISO 10390:2022-09
167 Sewage sludge Loss on ignition / organic matter
Range (10 – 90) %
Gravimetric method PN-EN 15935:2022-01
168 Waste gases Concentration / content of aromatic hydrocarbons
benzene (0,50 – 20000) μg in the sample Range (0,0333 – 1333) mg/m3 toluene (0,50 – 20000) μg per sample (0,0333 – 1333) mg/m3 ethylbenzene (0,50 – 20000) μg in sample (0,0333 – 1333) mg/m3 xylene (0,50 – 20000) μg in sample (0,0333 – 1333) mg/m3 ethyl acetate (1,0 – 20000) μg in sample (0,0667 – 1333) mg/m3 butyl acetate (1,0 – 20000) μg in sample (0,0667 – 1333) mg/m3 styrene (0,50 – 20000) μg per sample (0,0333 – 1333) mg/m3 acetone (5,0 – 20000) μg in the sample (0,333 – 1333) mg/m3
Gas chromatography with flame ionization detection (GC-FID) PN-EN 13649:2005
169 Waste gases Concentration / content of aliphatic hydrocarbons (C6-C14)
hexane (1,0 – 20000) μg in sample Range (0,0667 – 1333) mg/m3 heptane, octane, nonane, decane, undecane, dodecane, tridecane, tetradecane (0,50 – 20000) μg in sample (0,0333 – 1333) mg/m3
Gas chromatography with flame ionization detection (GC-FID) PN-EN 13649:2005

Reference standards (94)

ISO 13320:2020
PB-026/WA issue 7 of 15.07.2019
PB-049/WA issue 3 of 15.07.2019
PB-058/WA issue 4 of 15.07.2019
PB-059/WA issue 4 of 15.07.2019
PB-060/WA issue 2 of 15.07.2019
PB-062/WA issue 2 of 15.07.2019
PB-067/WA issue 3 of 01.07.2023
PB-068/WA issue 2 of 15.07.2019
PB-072/WA issue 1 of 28.09.2020
PB-073/WA issue 2 of 30.05.2022
PB-075/WA issue 1 of 01.06.2022
PB-09/CLB issue 1 of 30.05.2022
PB-11/CLB issue 1 of 25.09.2023
PN-77/C-04584
PN-77/C-04604.08
PN-82/C-04576/08
PN-86/C-04573.01
PN-86/C-04573/01
PN-EN 10694:2002 excluding cl. 8.2.1
PN-EN 12619:2013
PN-EN 12880:2004
PN-EN 13284-1:2018-02
PN-EN 13342:2002
PN-EN 13346:2002
PN-EN 13649:2005
PN-EN 14039:2008
PN-EN 14385:2005
PN-EN 14789:2017-04
PN-EN 14790:2017-04
PN-EN 14792:2017-04
PN-EN 1484:1999
PN-EN 15058:2017-04
PN-EN 15216:2022-03
PN-EN 15935:2022-01
PN-EN 16171:2017-02
PN-EN 16174:2012
PN-EN 1899-2:2002
PN-EN 25663:2001
PN-EN 26777:1999
PN-EN 27888:1999
PN-EN 872:2007+Ap1:2007
PN-EN 903:2002
PN-EN ISO 10304-1:2009+AC:2012
PN-EN ISO 10390:2022-09
PN-EN ISO 10523:2012
PN-EN ISO 11732:2007 excluding cl. 3
PN-EN ISO 11885:2009
PN-EN ISO 13395:2001
PN-EN ISO 14402:2004 excluding cl. 3
PN-EN ISO 14403-1:2012
PN-EN ISO 14911:2002
PN-EN ISO 15680:2008
PN-EN ISO 16703:2011
PN-EN ISO 16911-1:2013-07 CEN/TR 17078:2017-03
PN-EN ISO 17294-2:2024-04
PN-EN ISO 17852:2009
PN-EN ISO 22155:2016-07
PN-EN ISO 5667-13:2011
PN-EN ISO 5667-6:2016-12 excluding cl. 7.5, 7.6
PN-EN ISO 5814:2013
PN-EN ISO 5815-1:2019-12
PN-EN ISO 6468:2002
PN-EN ISO 6878:2006 +Ap1:2010+Ap2:2010
PN-EN ISO 6878:2006 +Ap1:2010+Ap2:2010 cl. 7
PN-EN ISO 6878:2006+Ap1:2010+ Ap2:2010 cl. 4
PN-EN ISO 6878:2006+Ap1:2010+ Ap2:2010 cl. 4, cl. 7, cl. 8
PN-EN ISO 6878:2006+Ap1:2010+Ap2:2010
PN-EN ISO 6878:2006+Ap1:2010+Ap2:2010 cl. 4
PN-EN ISO 8467:2001
PN-EN ISO 9377-2:2003
PN-ISO 10260:2002
PN-ISO 10381-4:2007
PN-ISO 10381-5:2009
PN-ISO 10382:2007
PN-ISO 10396:2001
PN-ISO 11423-1:2002
PN-ISO 11465:1999
PN-ISO 15705:2005
PN-ISO 5664:2002
PN-ISO 5667-10:2021-11
PN-ISO 5667-11:2017-10
PN-ISO 6059:1999
PN-ISO 7150-1:2002
PN-ISO 9280:2002
PN-ISO 9297:1994
PN-Z-04008-4:1999
PN-Z-04030-7:1994
Clause 3 of the Annex to the Regulation of the Minister of Climate of 17.02.2020 (Journal of Laws 2022 item 2630)
Annex to the Regulation of the Minister of Climate of 17.02.2020 (Journal of Laws 2022 item 2630)
Annex 2 to the Regulation of the Minister of the Environment of 16.06.2011 (Journal of Laws 2011 No. 140, item 824) excluding cl. H
Annex 3 to the Regulation of the Minister of the Environment of 16.06.2011 (Journal of Laws 2011 No. 140 item 824 and No. 288, item 1697) excluding cl. H
Annex 7 to the Regulation of the Minister of Climate and Environment of 07.09.2021 (consolidated text Journal of Laws of 2023, item 1706) excluding cl. F
Annex 8 to the Regulation of the Minister of Climate and Environment of 07.09.2021 (consolidated text Journal of Laws of 2023, item 1706)

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